HBr–DMPU: The First Aprotic Organic Solution of Hydrogen Bromide
نویسندگان
چکیده
منابع مشابه
Counteranion-dependent mechanisms of intramolecular proton transfer in aprotic solution.
Using the freon mixture CDF(3)/CDClF(2) as solvent we have been able to measure the (1)H and (15)N NMR spectra of the doubly (15)N labeled 2,2'-bipyridinium cation (BpyH(+)) at temperatures down to 115 K. The obtained NMR parameters strongly depend on the type of counteranions indicating the formation of ion pairs. In the case of the bulky poorly coordinating tetrakis[3,5-bis(trifluoromethyl)ph...
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Photodissociation dynamics of HBr at a series of photolysis wavelengths in the range of 123.90-125.90 nm and at around 137.0 nm have been studied using the H atom Rydberg "tagging" time-of-flight technique. The branching fractions between the channels forming ground Br((2)P3/2) and spin-orbit excited Br((2)P1/2) atoms together with the angular distributions of the products corresponding to thes...
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within the components of communicative competence, a special emphasis is put on the “rules of politeness,” specifically the politeness strategies (brown and levinson, 1978) that speakers deploy when performing the request speech act. this is because the degree of imposition that making a request places upon one’s interlocutor(s) has been seen to be influenced by several factors among which, as ...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2017
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.201703457